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CAS Number: 82689-19-8
(S)-tert-butyl 1-hydroxy-3-(1H-indol-3-yl)propan-2-ylcarbamate

Structure

(S)-tert-butyl 1-hydroxy-3-(1H-indol-3-yl)propan-2-ylcarbamate
Name: (S)-tert-butyl 1-hydroxy-3-(1H-indol-3-yl)propan-2-ylcarbamate
Synonyms:
General Information
Product Number: 82689198
 
CAS Number:
82689-19-8
Name:
(S)-tert-butyl 1-hydroxy-3-(1H-indol-3-yl)propan-2-ylcarbamate
Formula:
C16H22N2O3
Molecular Weight:
290.36
Synonyms:
Carbamicacid, [(1S)-2-hydroxy-1-(1H-indol-3-ylmethyl)ethyl]-, 1,1-dimethylethyl ester(9CI);Carbamic acid, [2-hydroxy-1-(1H-indol-3-ylmethyl)ethyl]-,1,1-dimethylethyl ester, (S)-;1,1-Dimethylethyl[(1S)-2-hydroxy-1-(1H-indol-3-ylmethyl)ethyl]carbamate;N-tert-Butoxycarbonyl-L-tryptophanol;Boc-Trp-ol;Boc-Tryptophanol;
InChI: InChI=1S/C16H22N2O3/c1-16(2,
3)21-15(20)18-12(10-19)8-11-9-17-14-7-5-4-6-13(11)14/h4-7,9,12,17,19H,8,
10H2,1-3H3,(H,18,20)/t12-/m0/s1
InChIKey: JEFQUFUAEKORKL-LBPRGKRZSA-N
Canonical SMILES : CC(C)(C)OC(=O)NC(CC1=CNC2=CC=CC=C21)CO
 
 
Optical and Scattering Properties Value Condition Note
Optical Rotatory Power -19.1 ° Solv: dichloromethane (75-09-2) (1)CAS
Optical Rotatory Power -22.2 ° Conc: 1 g/100mL; Solv: methanol (67-56-1); Wavlen: 589.3 nm; Temp: 25 °C (2)CAS
Optical Rotatory Power See full text   (3)CAS
Thermal Properties Value Condition Note
Melting Point 118-120 °C   (1)CAS
Melting Point 110-112 °C   (4)CAS
Melting Point 99-103 °C   (2)CAS
Melting Point See full text   (3)CAS

Specification

98%

References
  1. (1) Ragains, Justin R.; Organic Letters 2006, V8(20), P4437-4440 CAPLUS
  2. (2) Jadhav, Sandip V.; Organic & Biomolecular Chemistry 2011, V9(11), P4182-4187 CAPLUS
  3. (3) Srivastava, Tumul; Journal of Chemical Research, Synopses 2003, (8), P516-517 CAPLUS
  4. (4) Juszczyk, Paulina; Letters in Peptide Science 2004, V10(2), P79-82 CAPLUS
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