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CAS Number: 12354-85-7
Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]

Structure

Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]
Name: Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]
Synonyms:
General Information
Product Number: 12354857
CAS Number:
12354-85-7
Name:
Rhodium, di-m-chlorodichlorobis[(1,2,3,4,5-h)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]di-(9CI)
Formula:
C20H30Cl4Rh2
Molecular Weight:
618.08
Synonyms:
1,3-Cyclopentadiene,1,2,3,4,5-pentamethyl-, rhodium complex;Bis(chloro(m-chloro)(h5-pentamethylcyclopentadienyl)rhodium);Bis(pentamethylcyclopentadienylrhodium dichloride);Bis(m-chloro)bis(chloro(h5-pentamethylcyclopentadienyl)rhodium);Di-m-Chlorodichlorobis(pentamethyl-p-cyclopentadienyl)dirhodium;Di-m-chlorobis[chloro(h5-pentamethylcyclopentadienyl)rhodium];Di-m-chlorodichlorobis((h5-pentamethylcyclopentadienyl)rhodium);Dichloro(pentamethylcyclopentadienyl)rhodium(II) dimer;Tetrachlorobis(pentamethylcyclopentadienyl)dirhodium;Tetrachlorobis(h5-pentamethylcyclopentadienyl)dirhodium;
InChI: InChI=1S/2C10H15.4ClH.2Rh/c2*1-6-7(2)9(4)10(5)8(6)3;;;;;;/h2*1-5H3;4*1H;;/q2*-1;;;;;2*+3/p-4
InChIKey: AUBQNRPCZLEJIZ-UHFFFAOYSA-J
Canonical SMILES : C[C-]1C(=C(C(=C1C)C)C)C.C[C-]1C(=C(C(=C1C)C)C)C.Cl[Rh+]Cl.Cl[Rh+]Cl
Deleted CAS Registry Numbers: 51160-00-0, 60867-02-9
 Melting Point:
>300 °C
Appearance:
burgundy solid
Hazard Symbols:
Xn
Risk Codes:
20/21/22-36/37/38
Safety:
26-36

Specification

98%

References
  1. (1) WSS: Spectral data were obtained from Wiley Subscription Services, Inc. (US)
  2. (2) Liu, Guohua; Advanced Synthesis & Catalysis 2011, V353(8), P1317-1324 CAPLUS
  3. (3) Buryak, Andrey; Chemical Communications (Cambridge, United Kingdom) 2007, (23), P2366-2368 CAPLUS
  4. (4) Too, Pei Chui; Journal of Organic Chemistry 2011, V76(15), P6159-6168 CAPLUS
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